After every three full days of voting, the cardinals break for a day of prayer and reflection, then resume for another three days. The first pause will be on Saturday if no pope has been selected before that.
THE SMOKE
Smoke will emerge from the chimney once at the end of the morning session — about 12 p.m. (7 a.m. EDT; 1100 GMT) — and again at the end of the afternoon session — about 7 p.m. (2 p.m. EDT; 1800 GMT). But if an earlier vote yields a pope, white smoke would emerge at that time, ending the conclave.
Once white smoke emerges from the chimney, a bell at the St. Peter’s Basilica rings. Within an hour, the man who was selected emerges onto the balcony and his identity is known.
via Schedule of voting during the papal conclave » Times Record News.